Sodium borohydride 16940662 60 100% all concentrations are percent by weight unless ingredient is a gas. Material safety data sheet sodium hydroxide solution. It is preferred to sodium cyanoborohydride nabh3cn in many applications due to reduced toxicity of the. Water, acid, or high temperatures can liberate flammable hydrogen gas. It is incompatible with oxidizing agents and alkali metals. Safety data sheet northwest missouri state university. Sodium borohydride nabh4 is a mild reducing agent that is typically used to reduce aldehydes and ketones to their respective alcohols. Sodium borohydride 16940662 100 toxicological data on ingredients. Sodium borohydride nabh 4 was used as a reducing agent for coprecipitation of nanoparticles. In the final set of experiments, sodium borohydride could be successfully produced by using trimethyl borate and sodium hydride in a disc mill at 50oc under 10 bars hydrogen pressure. Properties of aqueous alkaline sodium borohydride solutions and byproducts formed during hydrolysis presented at the fuel cell design, fabrication and materials selection workshop grainger engineering library, room 335 1 w. Hydrogen can be easily produced from the catalytic hydrolysis of sodium borohydride nabh4, with sodium metaborate nabo2 being the coproduct. Identification product name sodium borohydride cat no. Sodium borohydride applications has many uses including the following.
Sodium borohydride msds material safety data sheet or sds, coa and coq, dossiers, brochures and other available documents. Incompatible materials strong oxidizing agents, aldehydes, ketones, acids, aluminium. May damage the unborn child precautionary statements prevention obtain special instructions before use. Central drug house p ltd 728 vardaan house new delhi2 india. Material safety data sheet sodium borohydride 1 chemical product and company identification msds name. Sodium borohydride revision date 17jan2018 stability water reactive. Certificate of analysis coa bulletin pdf specification sheet pdf raman ftir pdf. R35, symbol and r phrase according to ec annex1 subject to the reporting requirements of sara title iii section 3. Sodium borohydride 16940662 tokyo chemical industry co. A method for the regeneration of sodium borohydride from its hydrolysis product, sodium borate, is described. We have tried to make it as accurate and useful as possible, but can take no responsibility for its use, misuse, or accuracy. The present laboratory examines the use of sodium borohydride nabh 4 in ethanol, as shown below. As a result of thermal decomposition, dangerous products can form. Sodium borohydride nabh4 or bh4na cid 4311764 structure, chemical names, physical and.
Fire and explosion risk in contact with oxidizing agents. Practically speaking, a chemist will use one equivalent of sodium borohydride to reduce an aldehyde or ketone. This information was last updated on september 4, 2003. And under the appropriate conditions, this versatility expands to include stereoselective reductions 3. Nabh4 is sometimes used to reduce esters to alcohols but the reaction is generally slow. University illinois urbana champaign urbana, illinois 61801 july 2627, 2005 by. Sds of sodium borohydride, safety data sheets, cas 16940662. Safety data sheet creation date 29jan2010 revision date 17jan2018 revision number 4 1. Fisher scientific 1 reagent lane fair lawn, nj 07410 for information, call. It is in fact used during the manufacture of paper, in order to bleach the natural colour. Sodium molybdate is used as a micronutrient for plants and animals. Other articles where sodium tetrahydridoborate is discussed. This white solid, usually encountered as a powder, is a. Regeneration of sodium borohydride from sodium metaborate.
Sodium tetrahydridoborate chemical compound britannica. Nucleophilic addition of hydride ion from sodium borohydride is an inexpensive alternative method for the baylishillman reaction to form e. First aid measures general advice consult a physician. Sodium triacetoxyborohydride nabh oac3 is particularly effective in reductive aminations due to its large scope, mildness, and selectivity. Safety data sheet 111531 sodium borohydride granular. Sodium borohydride revision date 17jan2018 attention is required. Chemical product and company identification product name. Water, acid, or high temperatures can liberate flammable. Material safety data sheet sodium borohydride msds section 1.
Properties of aqueous alkaline sodium borohydride solutions and byproducts formed during hydrolysis presented at the fuel cell design, fabrication and materials selection workshop. Pyridine acs safety data sheet according to the federal final. Xray diffraction xrd analysis showed the presence of fe 3 o 4. Application nanocrystalline superlattices in gold colloid solution have been prepared by ligandinduction using aucl 3 reduced with sodium borohydride. The msds was formatted to comply with ansi standard z400. This product has been replaced by 452882aldrich sodium borohydride powder.
Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Nabh4 is sometimes used to reduce esters to alcohols but the. Which is better to use, product 316393, sodium triacetoxyborohydride, or sodium cyanoborohydride. If you would store it without taking special precautions, the powder will form a cake and loose some of its reductive strenght. In contact with water releases flammable gases which may ignite spontan eously. Hazards identification potential acute health effects. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids. Preparation of potassium borohydride by a mechanochemical reaction of saline hydrides with dehydrated borate through ball milling. Shut off ignition sources and call fire department. Extremely hazardous in case of skin contact irritant, of eye contact irritant, of ingestion, of inhalation.
In case of more serious fires, also alcoholresistant foam and water spray. Sodium borohydride is a white to grayish crystalline powder. Formation of hazardous combustion gases or vapors possible in the event of fire. Wear rubber overclothing including gloves and dust respirator. These include nabh4 for energy systems such as direct borohydride fuel. Progress in sodium borohydride as a hydrogen storage. Sodium borohydride, its hydrolysis and its use as a. Sodium borohydride 16940662 x026110ul borohydride stock 9. Aluminum, tin, zinc, sodium borohydride, chlorine dioxide, nitrosomethylurea, tetrahydrofuran, maleic anhydride, nitrogen trichloride, nitrolalkanes, 2,4,5. Hailong jiang, sanjay kumar singh, junmin yan, xinbo zhang, qiang xu.
Properties of aqueous alkaline sodium borohydride solutions. Do not use mouthtomouth method if victim ingested or inhaled the substance. Sodium borohydride 16940662 sodium tetrahydroborate sodium borohydride nabh4 contact information. Sodium borohydride is a strong reducing agent, meaning in a chemical reaction it will reduce another substance. Preliminary information on manufacturing, processing, distribution, use, and. Sodium molybdate with will violently react with interhalogens e. Sodium borohydride nabh4 determination, both qualitative and quantitative, is of great significance in a plethora of areas.
Excess molybdenum in some animals may result in a molybdenum induced copper deficiency known as molybdenosis. Buy sodium borohydride cas 16940662, a strong reducing agent used in organic and biochemical reactions, from santa cruz. Firstaid measures general advice immediate medical attention is required. Safety data sheet creation date 07dec2009 revision date 23jan2018 revision number 5 1. This article will examine a few typical industrial examples showing sodium borohydride as a chemoselective and stereoselective. Sodium borohydride cas 16940662 818823 merck millipore. Like many metal hydrides, it undergoes hydrolysis in the presence of water.
Hydrochloric acid uk oes stel 7 mgm3 10 minutes usa osha pel 7 mgm3 ceiling usa acgih 7 mgm3 tlv ceiling usa niosh 7 mgm3 ceiling canada tlv 7 mgm3 osha idlh 50 ppm vle france. Preliminary information on manufacturing, processing. Sodium borohydride nabh 4 has attracted significant attention as a potential hydrogen storage material over the past decade. Identification product name sodium borohydride, 12% solution in 40% aq. Borohydride donates a hydride to the carbonyl carbon, generating borane, which is a weaker reducing agent than borohydride. Sodium borohydride sbh cautionary response information common synonyms solid powder or pellets white odorless sinks and mixes with water. We have tried to make it as accurate and useful as possible, but can take no responsibility for its use, misuse, or. Ph eur the safety data sheets for catalogue items are available at. In the final set of experiments, sodium borohydride could be. Industry applications producers of sodium borohydride. To minimize caking, i store my nabh4 in 250 g plastic containers do not use glass. Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, is an inorganic compound with the formula na bh 4.
Pyridine acs safety data sheet according to the federal final rule of hazard communication revised on 2012 hazcom 2012 jubilant life sciences limited page 3 of 10 with the aid of a pocket mask. Sodium borohydride hydrolysis as hydrogen generator. Sodium hydride material safety data sheet cas no 7646697. This fact sheet is a summary source of information of all potential and most severe health hazards that may result from. Identification of the substancemixture and of the company undertaking 1. Sodium or potassium borohydride can also be used insitu to produce other more aggressive reducing agents cost effectively. Metal recovery sodium borohydride is extremely effective in reducing metal.
Pyridine acs safety data sheet according to the federal. Sodium borohydride, its hydrolysis and its use as a reducing. Pyridine acs safety data sheet according to the federal final rule of hazard communication revised on 2012 hazcom 2012 jubilant life sciences limited page 1 of 10. Merck safety data sheet according to regulation ec no.
Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Sodium borohydride is a moisturesensitive substance. Sodium borohydride can be easily modified to form either a stronger or more selective reducing agent 2. Page 2 of 6 environmental precautions do not empty into drains. The dried borate salt was converted to a series of sodium tetraalkoxyborates prior to.
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